Zane and Steve check in to Music City: Nashville, Tennessee. They start their day off with a liter beer race, visit a modern moonshine distillery, and put their whiskey knowledge to the test. They learn to carbonate their own cocktails, and then join a roller derby team for a race around the rink.

Zane and Steve hike their way through the "Land of the Sky". In an effort to embrace Asheville's newly won title as "Beer City USA", Zane and Steve attempt a pub crawl to each brewery in the city.

Known as "The Queen City" and "Home of Nascar", they visit the area's only beer garden to make some cheese, discover a way to pair their love of chocolate with liquor, and get into a fight with a crawfish.