Six top winners in Master Distiller history face off in a grand elimination tournament where they must design elaborate still builds and run backwoods liquors from raw ingredients. Popcorn Sutton's spouse, Pam Sutton joins judges Mark, Digger and Tim.

Mark, Digger and Tim raise the stakes in the tournament as Mark Rogers joins as guest judge. The legendary mountain man devises a bootlegging twist to challenge the five remaining Master Distillers now competing for just 3 slots in the semi-final round.

Three Master Distiller champions remain in the grand elimination tournament, but only two will survive. With Josh Owens as guest judge, Mark, Digger and Tim ramp up the stakes with one of the most challenging and legendary backwoods spirits, Cherry Bounce.