Brad Pitt and Angelina Jolie's relationship seemed perfect and made headlines from day one, but all illusions came crashing down just two years after their wedding.

Roseanne Barr and Tom Arnold's tabloid-ready marriage, from out-of-control spending and wild behavior on the 'Roseanne' set to Barr's dabbling in plastic surgery, was chronicled meticulously by the press.[Slice Channel]

Alec Baldwin and Kim Basinger were a seemingly perfect couple who generated envy all across Hollywood, but beneath their glamorous appearance, a highly dysfunctional relationship loomed.